هحتوى هقرراث برناهج الذبلوم الخاص العذاد الوعلن "تخظض ك و اء عضو ت"
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1 هحتوى هقرراث برناهج الذبلوم الخاص العذاد الوعلن "تخظض ك و اء عضو ت" للعام الجاهع جاهعت ع ن شوس كل ت الترب ت قسن الك و اء
2 توط ف هقرر ك و اء عضو ت )1(: اسن الوقرر : Organic 1: Spectroscopy I: IR, UV and Mass Spectrometry الوستوى: Special Diploma عذد الوحذاث الذراصيت : (hrs/week( 2 نظر ---- عول الرهز الكود : CHO601 التخظض : Organic 1. Types of molecular vibrations. 2. IR, UV and mass spectra instrumentation. 3. Identification of molecular structure. 4. Introduction to the science of spectroscopy. 5. Introduction of the electromagnetic spectrum. 6. Description the great differences in the infrared, electronic and rotational motions in the electromagnetic radiation. 7. The basic concepts in UV spectroscopy. 8. The instrumentation of UV spectroscopy. 9. Getting charts of UV spectrum. 10. The basic concepts in IR spectroscopy. 11. The instrumentation of IR spectroscopy. 12. Getting charts of IR spectrum. 13. The basic concepts in MS spectroscopy. 14. The instrumentation of MS spectroscopy. 15. Getting charts of MS spectrum. 16. The parent peak in the mass spectra. 17. Interpretation of the mass spectrum. 18. Examples with different function groups in molecules. 19. Determination the molecular weight in the sample. 4.Course Content أصتار المادة : أ.د. حافظ الشاعر رئيش مجلش القضم العلم : أ.د. محمود مشالي جامعه عين شمش
3 كليت التربيه قضم الكيمياء توط ف هقرر ك و اء عضو ت )2 (: الوستوى : Diploma Special ---- عول : Organic 2: Spectroscopy II: NMR Spectroscopy اصم المقرر عذد الوحذاث الذراصيت : (hrs/week( 2 نظر الرهز الكود : CHO602 التخظض : Organic 1.Phenomenon of NMR H, 13 C-NMR instrumentation. 3.Chemical shift as a function of structure of organic molecule. 4.Theory of the chemical shift. 5.Spin-spin coupling. 6.Naming of protons in molecules. 7.Protons of hetero-atom. 8.Carbon-13 NMR spectrum 9.The relation between the chemical shift and the s- character in the carbon atom in sp, sp2 and sp3 hybridization. 10. Nuclear Over housing Effect 11. Relaxation time T1 and T2 in the carbon-13 nuclei. 12. Anisotropic effect 13. NMR correlation between H-NMR and C-NMR. 14. Notes on other different of 31 P-, 17 O- and 15 N-NMR الوقرر : 4. Course Content 2- محتوى أستار الوادة : د. طارق الس ذ عل رئ س هجلس القسن العلو : أ.د. هحوود هشالي جامعه عين شمش كليت التربيه قضم الكيمياء
4 توط ف هقرر ك و اء عضو ت )3(: اصم المقرر : Organic 3: Heterocyclic. عذد الوحذاث الذراصيه : hr/week) 3) نظر المضتوى: Special Diploma عمل 1. Introduction: Importance of heterocycles, natural heterocyclic compounds. 2. IUPAC Nomenclature rules and nomenclature of more than one heteroatom containing rings and condensed systems 3. Structure and main physical properties of aromatic heterocycles 4. General basis of synthesis of aromatic heterocycles 5. Pyridine; General discussion and comparison with benzene 6. Pyridine; Reaction and synthesis 7. Quinolines and Isoquinolines; Comparison with pyridine and naphthalene 8. Quinolines; Reactions and Synthesis 9. Diazines; Pyrimidine comparison with pyridine 10. Diazines; comparison with each other 11. Diazines; reactions and synthesis 12. Benzodiazines: quinoxaline, quinazulines, phthalazines 13. Triazines, Tetrazines; General comparison 14. Pyrans, pyrones, and pyrylium salts comparison with pyridines 15. Coumarins and chromones; general discussion 16. Coumarins and chromones; reactions and synthesis 17. Indole, Isoindole, Benzofuran and Benzothiophene; Comparison with indole 18. 1,3-Diazoles; imidazole, oxazole, and thiazole: General discussion and comparison with monoazoles and pyridine 19. 1,3-Diazoles; reactions and synthesis 20. 1,2-Diazoles; General discussion and comparison with 1,3-diazoles 21. 1,2-Diazoles; reactions and synthesis الرمز الكود : CHO603 التخصص: Organic Course Content
5 22. Triazoles and Tetrazoles 23. Small Heterocycles; Three and four membered heterocycles. 24. Large Heterocycles; Seven and Eight-membered heterocycles رئ س القسن: أ.د. هحوود هشالي أستار الوادة: د. طارق الس ذ علي جامعت عين شمش كليت التربيه قضم الكيمياء توط ف هقرر ك و اء عضو ت )4(: الوستوى : Diploma Special عمل الرهز الكود : CHO604 التخصص : Organic اصم المقرر Organic 4: Selected Topics: Aromaticity, Delocalized Chemical bonding, and Aromatic Nucleophilic Substitution عذد الوحذاث الذراصيه : (2hrs/week) نظر
6 Delocalized Chemical Bonding: 1. Localized and delocalized bonds. 2. Bond distances and energies in compounds containing delocalized bonds. 3. Kinds of molecules that have delocalized bonds. 4. Conjugation and rules of resonance. 5. Resonance effect. 6. Steric inhibition of resonance and the Influences of Strain. 7. p -d Bonding: Ylids. 8. Hyperconjugation. 9. Tautomerism Keto Enol Tautomerism 9.2. Phenol Keto Tautomerism 9.3. Nitroso Oxime Tautomerism Aliphatic Nitro Compounds Are in Equilibrium with Aci Forms Imine Enamine Tautomerism Ring-Chain Tautomerism. II. Aromaticity: 1. Recent definitions; diatropism and paratropism. 2. Aromaticity and antiaromaticity on lights of diamagnetism and paramagnetism phenomena. 3. Six-membered homo- and heterocyclic aromatic rings. 4. Partial bond fixation. 5. Fused rings and annellation. 6. Five-, seven-, and eight-membered homo- and heterocyclic aromatic rings. 7. Other Systems Containing Aromatic Sextets. 8. Aromatic Systems with Electron Numbers Other Than Six and Huckel s rule. 9. Systems of Two Electrons. 10. Systems of Four Electrons. 11. Systems of Eight Electrons. 12. Systems of Ten Electrons. 13. Systems of More than Ten Electrons: 4n+ 2 Electrons. 14. Systems of More Than Ten Electrons: 4n Electrons. 15. Other Aromatic Compounds: Mesoionic Compounds The Dianion of Squaric Acid Homoaromatic Compounds Fullerenes. III. Aromatic Nucleophilic Substitution 1. The S N Ar Mechanism. 2. The S N 1 Mechanism. 3. The Cyne or Aryne Mechanism. 4. The S RN 1 Mechanism. 5. Other Mechanisms: 6. Reactivity: 6.1. The Effect of Substrate Structure The Effect of the Leaving Group The Effect of the Attacking Nucleophile..Course Content2 أصتار المادة : : أ.د. دمحم عباس دمحم رئيش القضم: أ.د. محمود مشالي
7 جامعت عين شمش كليت التربيه قضم الكيمياء توط ف هقرر ك و اء عضو ت )4(: الرهز الكود : CHO604 اصم المقرر Organic 4: Selected Topics: Aromaticity, Delocalized Chemical bonding, and Aromatic Nucleophilic Substitution الوستوى : Diploma Special التخصص : Organic عذد الوحذاث الذراصيه : (2hrs/week) نظر عمل
8 Delocalized Chemical Bonding: 1. Localized and delocalized bonds. 2. Bond distances and energies in compounds containing delocalized bonds. 3. Kinds of molecules that have delocalized bonds. 4. Conjugation and rules of resonance. 5. Resonance effect. 6. Steric inhibition of resonance and the Influences of Strain. 7. p -d Bonding: Ylids. 8. Hyperconjugation. 9. Tautomerism Keto Enol Tautomerism 9.2. Phenol Keto Tautomerism 9.3. Nitroso Oxime Tautomerism Aliphatic Nitro Compounds Are in Equilibrium with Aci Forms Imine Enamine Tautomerism Ring-Chain Tautomerism. II. Aromaticity: 1. Recent definitions; diatropism and paratropism. 2. Aromaticity and antiaromaticity on lights of diamagnetism and paramagnetism phenomena. 3. Six-membered homo- and heterocyclic aromatic rings. 4. Partial bond fixation. 5. Fused rings and annellation. 6. Five-, seven-, and eight-membered homo- and heterocyclic aromatic rings. 7. Other Systems Containing Aromatic Sextets. 8. Aromatic Systems with Electron Numbers Other Than Six and Huckel s rule. 9. Systems of Two Electrons. 10. Systems of Four Electrons. 11. Systems of Eight Electrons. 12. Systems of Ten Electrons. 13. Systems of More than Ten Electrons: 4n+ 2 Electrons. 14. Systems of More Than Ten Electrons: 4n Electrons. 15. Other Aromatic Compounds: Mesoionic Compounds The Dianion of Squaric Acid Homoaromatic Compounds Fullerenes. III. Aromatic Nucleophilic Substitution 1. The S N Ar Mechanism. 2. The S N 1 Mechanism. 3. The Cyne or Aryne Mechanism. 4. The S RN 1 Mechanism. 5. Other Mechanisms: 6. Reactivity: 6.1. The Effect of Substrate Structure The Effect of the Leaving Group The Effect of the Attacking Nucleophile..Course Content2 أصتار المادة : : أ.د. دمحم عباس دمحم رئيش القضم: أ.د. محمود مشالي
9 جاهعت ع ن شوس كل ت الترب ه قسن الك و اء توط ف هقرر ك و اء عضو ت )6(: اسن الوقرر : Organic 6: Organic Reactions الوستوى : Diploma Special عذد الوحذاث الذراس ت : )2hrs/week( نظر عول الرهز الكود : CHO606 التخظض : Organic 1. Chapter I : Oxidation in organic compounds 1.1 Oxidation of methylene group Oxidation by selenium dioxide. 1.3 Epoxidation and hydroxylation. 1.4 Ozone as oxidant. 1.5 Degradation of side chain. 1.6 Oxidation of sulfur. 2. Chapter II : Reduction in organic compounds 2.1 Reduction of aliphatic hydrocarbons. 2.2 Reduction of aromatic hydrocarbons 2.3 Reduction of carbonyl compounds. 2.4 Reduction of nitrogen compounds. 2.5 Hydrogenation and hydrogenolsis. 2.6 Dehydrogenation and desulfurization. 2.7 Pyrolysis of anhydrides and esters. 2.8 Molecular reactions. 3- Chapter III: Some reactions with aromatic compounds 3.1. Alkylation 3.2. Acylation 3.3. Ring closure reactions in organic compounds رئ س القسن: أ.د. هحوود هشالي 4.Course Content أستار الوادة : أ.د. س جبر جاهعت ع ن شوس كل ت الترب ه قسن الك و اء توط ف هقرر ك و اء عضو ت )7(:
10 اصم المقرر : Organic 7 : Free Radicals Reactions المضتوى : Special Diploma عذد الوحذاث الذراصيت : )2hrs/week( نظر عمل الرهز الكود : CHO607 التخظض : Organic
11 1. -General discussion about what is mean by radical and detection of radical (Chemical and physical methods as ESR and CIDNP tech.). 2. Classification of radical reactions 4.Course Content a) Radical combination reactions b) Disproportination reaction c) Redox reactions d) Displacement (or substitution) reactions e) Addition reactions f) Fragmentation reactions g) Insertion reactions 3. Stability factors on radicals 4. 4-Structure of transition state a) Hammond postulate for the structure of T.S. b) Hammett equation for and determination of the structure of T.S. 5. Evaluation of radical stability a) By using bond dissociation data b) Ease of fragmentation c) Via selectivity of radicals Chemical kinetic of radical chain reactions 6. Stereochemistry of radicals 7. General methods for production of radicals a) photolysis or irradiation b) Redox reactions c) Electrolysis d) Using transition metal ions 8. Efficiency of radicals 9. Factors governing radical reactions 10. Nucleophilic and electrophilic radical reactions أستار الوادة: أ.د. هظطفي اسواع ل رئ س القسن: أ.د. هحوود هشالي
12 جاهعت ع ن شوس كل ت الترب ه قسن الك و اء توط ف هقرر ك و اء عضو ت )8(: الرهز الكود : CHO608 التخظض : Organic اصم المقرر : Organic 8: (A) Sulfur and Phosphorous (B) Organic Analytical الوستوى : Special Diploma عذد الوحذاث الذراصيت : )1hr/week( نظر عمل. Part (A): Sulphur and phosphorus Chapter I : Sulphur compound 1.1 Properties of sulfur atom in different molecules 1.2 Stability of sulfur compounds 1.3 Comparison between sulfur and oxygen compounds 1.4 Functional groups in sulfur compounds 1.5 Acceptable name for sulfur compounds 1.6 Importance of sulfa drugs 1.7 Spectral properties of sulfur compounds 2. Chapter II: Phosphorous compounds 2.1 properties of phosphorous atom in different molecules 2.2 Stability of phosphorous compounds 2.3 Comparison between phosphorous and nitrogen compounds 2.4 Acceptable name for phosphorous compounds 2.5 Spectral properties of phosphorous compounds Part (B): Organic Analytical 1. Gasometric Reaction 2. Determination of the Amine Function 3. Determination of the Azide Function 4. Determination of the Nitrate Function 5. Determination of the Carboxylate Function 6. Determination of the Sulfonic and Carbonyl 7. Oxidant and Reductant 8. Reductive Method 9. Oxidative Method 10. Acid Base Reaction.Course Content2 11. Direct And Indirect Acid Base Titration 12. Common Acid Base Theories 13. The Aqua metric Reaction 14. Chemical Method For Water Determination 15. Hydrolytic Method أستار الوادة: د. هجذى أحوذ د. وفاء رهزى رئ س القسن: أ.د. هحوود هشالي
13 جاهعت ع ن شوس كل ت الترب ه قسن الك و اء توط ف هقرر ك و اء عضو ت )8(: الرهز الكود : CHO608 التخظض : Organic اصم المقرر : Organic 8: (A) Sulfur and Phosphorous (B) Organic Analytical الوستوى : Special Diploma عذد الوحذاث الذراصيت : )1hr/week( نظر عمل. Part (A): Sulphur and phosphorus Chapter I : Sulphur compound 1.1 Properties of sulfur atom in different molecules 1.2 Stability of sulfur compounds 1.3 Comparison between sulfur and oxygen compounds 1.4 Functional groups in sulfur compounds 1.5 Acceptable name for sulfur compounds 1.6 Importance of sulfa drugs 1.7 Spectral properties of sulfur compounds 2. Chapter II: Phosphorous compounds 2.1 properties of phosphorous atom in different molecules 2.2 Stability of phosphorous compounds 2.3 Comparison between phosphorous and nitrogen compounds 2.4 Acceptable name for phosphorous compounds 2.5 Spectral properties of phosphorous compounds Part (B): Organic Analytical 1. Gasometric Reaction 2. Determination of the Amine Function 3. Determination of the Azide Function 4. Determination of the Nitrate Function 5. Determination of the Carboxylate Function 6. Determination of the Sulfonic and Carbonyl 7. Oxidant and Reductant 8. Reductive Method 9. Oxidative Method 10. Acid Base Reaction.Course Content2 11. Direct And Indirect Acid Base Titration 12. Common Acid Base Theories 13. The Aqua metric Reaction 14. Chemical Method For Water Determination 15. Hydrolytic Method أستار الوادة: د. هجذى أحوذ د. وفاء رهزى رئ س القسن: أ.د. هحوود هشالي
14
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